CobaltMaghrebV1, Maroc, Analysis, bibRecord, 000239

N-(2-pyridyl)-3-phenyl-2-propene amide (O-N) complexes of copper(II), nickel(II), cobalt(II) and palladium(II). Crystal and molecular structure of Cu(O-N)2(CF3SO3)2

Identifieur interne : 000239 ( Maroc/Analysis ); précédent : 000238; suivant : 000240

N-(2-pyridyl)-3-phenyl-2-propene amide (O-N) complexes of copper(II), nickel(II), cobalt(II) and palladium(II). Crystal and molecular structure of Cu(O-N)2(CF3SO3)2

Auteurs : ABDESSALAM BOUAYAD [Maroc] ; NAJIB BITIT [Maroc] ; E. Deydier [France] ; M.-J. Menu [France] ; M. Dartiguenave [France] ; Y. Dartiguenave [France] ; H. Duran [France] ; L. Gorrichon [France] ; M. Simard ; A. L. Beauchamp

Source :

Polyhedron [ 0277-5387 ] ; 1993.

RBID : Pascal:93-0339882

Descripteurs français

Pascal (Inist)
- Coordinat organique, Carboxamide, Préparation, Cuivre II Complexe, Nickel II Complexe, Cobalt II Complexe, Palladium II Complexe, Triflate, Cinnamique acide 2-pyridylamide, Structure cristalline, Diffraction RX, Etude expérimentale, Structure moléculaire.

English descriptors

KwdEn :
- Carboxamide, Cobalt II Complexes, Copper II Complexes, Crystalline structure, Experimental study, Molecular structure, Nickel II Complexes, Organic ligand, Palladium II Complexes, Preparation, X ray diffraction.

Abstract

The reaction of the title ligand N-(2-pyridyl)-3-phenyl-2-propene amide (O-N) with MX₂ salts yields compounds of the type M(O-N)₂X₂ and [M(O-N)₂(H₂O)₂]X₂, which were characterized by elemental analysis, magnetic moments and IR and EPR spectroscopies. From the IR spectra the ligand is found to be bidentate via the pyridyl nitrogen and the amide oxygen, except in [Pd(O-N)₂Cl₂] where only the pyridyl ring is coordinated.

Affiliations:

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Pascal:93-0339882

Le document en format XML

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(CF<sub>3</sub>
SO<sub>3</sub>
)<sub>2</sub>
</title>
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<author><name sortKey="Beauchamp, A L" sort="Beauchamp, A L" uniqKey="Beauchamp A" first="A. L." last="Beauchamp">A. L. Beauchamp</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">N-(2-pyridyl)-3-phenyl-2-propene amide (O-N) complexes of copper(II), nickel(II), cobalt(II) and palladium(II). Crystal and molecular structure of Cu(O-N)<sub>2</sub>
(CF<sub>3</sub>
SO<sub>3</sub>
)<sub>2</sub>
</title>
<author><name sortKey="Abdessalam Bouayad" sort="Abdessalam Bouayad" uniqKey="Abdessalam Bouayad" last="Abdessalam Bouayad">ABDESSALAM BOUAYAD</name>
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<sZ>1 aut.</sZ>
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<country>Maroc</country>
<wicri:noRegion>1776 Fès</wicri:noRegion>
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</author>
<author><name sortKey="Najib Bitit" sort="Najib Bitit" uniqKey="Najib Bitit" last="Najib Bitit">NAJIB BITIT</name>
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<s2>1776 Fès</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<wicri:noRegion>1776 Fès</wicri:noRegion>
</affiliation>
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<settlement type="city">Toulouse</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Menu, M J" sort="Menu, M J" uniqKey="Menu M" first="M.-J." last="Menu">M.-J. Menu</name>
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</affiliation>
</author>
<author><name sortKey="Dartiguenave, M" sort="Dartiguenave, M" uniqKey="Dartiguenave M" first="M." last="Dartiguenave">M. Dartiguenave</name>
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<s2>31062 Toulouse</s2>
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</author>
<author><name sortKey="Dartiguenave, Y" sort="Dartiguenave, Y" uniqKey="Dartiguenave Y" first="Y." last="Dartiguenave">Y. Dartiguenave</name>
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<country>France</country>
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</placeName>
</affiliation>
</author>
<author><name sortKey="Duran, H" sort="Duran, H" uniqKey="Duran H" first="H." last="Duran">H. Duran</name>
<affiliation wicri:level="3"><inist:fA14 i1="03"><s1>CNRS Univ. Paul Sabatier, lab. synthèse physicochimie organique</s1>
<s2>31062 Toulouse</s2>
<s3>FRA</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
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<country>France</country>
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</placeName>
</affiliation>
</author>
<author><name sortKey="Gorrichon, L" sort="Gorrichon, L" uniqKey="Gorrichon L" first="L." last="Gorrichon">L. Gorrichon</name>
<affiliation wicri:level="3"><inist:fA14 i1="03"><s1>CNRS Univ. Paul Sabatier, lab. synthèse physicochimie organique</s1>
<s2>31062 Toulouse</s2>
<s3>FRA</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Occitanie (région administrative)</region>
<region type="old region" nuts="2">Midi-Pyrénées</region>
<settlement type="city">Toulouse</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Simard, M" sort="Simard, M" uniqKey="Simard M" first="M." last="Simard">M. Simard</name>
</author>
<author><name sortKey="Beauchamp, A L" sort="Beauchamp, A L" uniqKey="Beauchamp A" first="A. L." last="Beauchamp">A. L. Beauchamp</name>
</author>
</analytic>
<series><title level="j" type="main">Polyhedron</title>
<title level="j" type="abbreviated">Polyhedron</title>
<idno type="ISSN">0277-5387</idno>
<imprint><date when="1993">1993</date>
</imprint>
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<seriesStmt><title level="j" type="main">Polyhedron</title>
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<idno type="ISSN">0277-5387</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Carboxamide</term>
<term>Cobalt II Complexes</term>
<term>Copper II Complexes</term>
<term>Crystalline structure</term>
<term>Experimental study</term>
<term>Molecular structure</term>
<term>Nickel II Complexes</term>
<term>Organic ligand</term>
<term>Palladium II Complexes</term>
<term>Preparation</term>
<term>X ray diffraction</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Coordinat organique</term>
<term>Carboxamide</term>
<term>Préparation</term>
<term>Cuivre II Complexe</term>
<term>Nickel II Complexe</term>
<term>Cobalt II Complexe</term>
<term>Palladium II Complexe</term>
<term>Triflate</term>
<term>Cinnamique acide 2-pyridylamide</term>
<term>Structure cristalline</term>
<term>Diffraction RX</term>
<term>Etude expérimentale</term>
<term>Structure moléculaire</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The reaction of the title ligand N-(2-pyridyl)-3-phenyl-2-propene amide (O-N) with MX<sub>2</sub>
 salts yields compounds of the type M(O-N)<sub>2</sub>
X<sub>2</sub>
 and [M(O-N)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
]X<sub>2</sub>
, which were characterized by elemental analysis, magnetic moments and IR and EPR spectroscopies. From the IR spectra the ligand is found to be bidentate via the pyridyl nitrogen and the amide oxygen, except in [Pd(O-N)<sub>2</sub>
Cl<sub>2</sub>
] where only the pyridyl ring is coordinated.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
<li>Maroc</li>
</country>
<region><li>Midi-Pyrénées</li>
<li>Occitanie (région administrative)</li>
</region>
<settlement><li>Toulouse</li>
</settlement>
</list>
<tree><noCountry><name sortKey="Beauchamp, A L" sort="Beauchamp, A L" uniqKey="Beauchamp A" first="A. L." last="Beauchamp">A. L. Beauchamp</name>
<name sortKey="Simard, M" sort="Simard, M" uniqKey="Simard M" first="M." last="Simard">M. Simard</name>
</noCountry>
<country name="Maroc"><noRegion><name sortKey="Abdessalam Bouayad" sort="Abdessalam Bouayad" uniqKey="Abdessalam Bouayad" last="Abdessalam Bouayad">ABDESSALAM BOUAYAD</name>
</noRegion>
<name sortKey="Najib Bitit" sort="Najib Bitit" uniqKey="Najib Bitit" last="Najib Bitit">NAJIB BITIT</name>
</country>
<country name="France"><region name="Occitanie (région administrative)"><name sortKey="Deydier, E" sort="Deydier, E" uniqKey="Deydier E" first="E." last="Deydier">E. Deydier</name>
</region>
<name sortKey="Dartiguenave, M" sort="Dartiguenave, M" uniqKey="Dartiguenave M" first="M." last="Dartiguenave">M. Dartiguenave</name>
<name sortKey="Dartiguenave, Y" sort="Dartiguenave, Y" uniqKey="Dartiguenave Y" first="Y." last="Dartiguenave">Y. Dartiguenave</name>
<name sortKey="Duran, H" sort="Duran, H" uniqKey="Duran H" first="H." last="Duran">H. Duran</name>
<name sortKey="Gorrichon, L" sort="Gorrichon, L" uniqKey="Gorrichon L" first="L." last="Gorrichon">L. Gorrichon</name>
<name sortKey="Menu, M J" sort="Menu, M J" uniqKey="Menu M" first="M.-J." last="Menu">M.-J. Menu</name>
</country>
</tree>
</affiliations>
</record>

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N-(2-pyridyl)-3-phenyl-2-propene amide (O-N) complexes of copper(II), nickel(II), cobalt(II) and palladium(II). Crystal and molecular structure of Cu(O-N)2(CF3SO3)2

N-(2-pyridyl)-3-phenyl-2-propene amide (O-N) complexes of copper(II), nickel(II), cobalt(II) and palladium(II). Crystal and molecular structure of Cu(O-N)2(CF3SO3)2

Source :

Descripteurs français

English descriptors

Abstract

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Links to Exploration step

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